杨峻山, 苏亚伦, 王玉兰, 冯孝章, 于德泉, 梁晓天. 蜜环菌菌丝体化学成分的研究——Ⅶ.丙酮提取物中化学成分的分离与鉴定J. 药学学报, 1991, 26(2): 117-122.
引用本文: 杨峻山, 苏亚伦, 王玉兰, 冯孝章, 于德泉, 梁晓天. 蜜环菌菌丝体化学成分的研究——Ⅶ.丙酮提取物中化学成分的分离与鉴定J. 药学学报, 1991, 26(2): 117-122.
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JS Yang, YL Su, YL Wang, XZ Feng, DQ Yu , XT Liang, . CHEMICAL CONSTITUENTS OF ARMILLARIA MELLEA MYCELIUM Ⅶ. ISOLATION AND CHARACTERIZATION OF CHEMICAL CONSTITUENTS OF THE ACETONE EXTRACTJ. Acta Pharmaceutica Sinica, 1991, 26(2): 117-122.
Citation: JS Yang, YL Su, YL Wang, XZ Feng, DQ Yu , XT Liang, . CHEMICAL CONSTITUENTS OF ARMILLARIA MELLEA MYCELIUM Ⅶ. ISOLATION AND CHARACTERIZATION OF CHEMICAL CONSTITUENTS OF THE ACETONE EXTRACTJ. Acta Pharmaceutica Sinica, 1991, 26(2): 117-122.
shu

蜜环菌菌丝体化学成分的研究——Ⅶ.丙酮提取物中化学成分的分离与鉴定

CHEMICAL CONSTITUENTS OF ARMILLARIA MELLEA MYCELIUM Ⅶ. ISOLATION AND CHARACTERIZATION OF CHEMICAL CONSTITUENTS OF THE ACETONE EXTRACT

    摘要
  • 摘要: 自人工液体发酵生产的白磨科(Tricholomataceae)蜜环菌Armiilaria meilea(Vahl.exFr.)Quel.菌丝体的丙酮提取物中分离得到八个化合物,其中三个为原伊鲁烷型倍半萜醇芳香酸酯类化合物。根据光谱(UV,IR,1H-NMR,13C-NMR,2D-NMR和MS)分析,其中一个为已知物4′-methylmelledonal(Ⅰ),两个为新化合物即密环菌丑素(armillaritin)和蜜环菌寅素(armillarivin),其结构分别为式Ⅱ和Ⅲ。另外五个为已知物赤藓醇(D-erythritol),甘露醇(Dmannitol),杜鹃花酸(azclaic acid)、苔藓酸(orsellinic acid)和甘油醇-α-单油酸酯(glycerin-α-monooleate)。

     

    Abstract: Eight compounds were isolated from the acetone extract of artificially cultutred mycelium of Armillaria mellea (Vahl. ex Fr.)Quel. (Tricholomataceae). Three of them are protoilludane sesquiterpenoid aromatic esters. Their structures were elucidated by spectral data analysis as the known 4′-methylmelledonal (Ⅰ)and two new compounds named armillaritin (Ⅱ) and armillarivin (Ⅲ). In addition, five known compounds were identified as D-erythritol, D-mannitol, azelaic acid, orsellinic acid and glycerin-α-monooleate.

     

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