玉柏石松三萜成分研究(英文)
Triterpenoid from Lycopodium obscurum L.
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摘要:
为了研究玉柏石松全草的三萜类成分, 运用正相和反相硅胶柱色谱技术对玉柏石松的乙酸乙酯提 取物进行分离纯化, 并运用波谱技术对其结构进行鉴定。共分离得到5个三萜类化合物, 其结构分别鉴定为3β, 19α-dihydroxy-20β-acetate-serrat-14-en-21β-ol (1), serratenediol (2), α-onocerin (3), 26-nor-8-oxo-α-onocerin (4), (3β, 8β, 14α, 21α)-26, 27-dinoronocerane-3, 8, 14, 21-tetrol (5)。其中化合物1为新的石松型三萜化合物, 化合物5为首次从该植物中分离得到。
Abstract:To study the triterpenoid constituents from air-dried whole plants of Lycopodium obscurum L., the constituents were isolated by normal-phase and reverse-phase silica gel column chromatorgraphy from the EtOAc extract. Their structures were elucidated on the basis of spectral analysis. Five triterpenoids were purified and identified as 3β, 19α-dihydroxy-20β-acetate-serrat-14-en-21β-ol (1), serratenediol (2), α-onocerin (3), 26-nor-8-oxo-α-onocerin (4), (3β, 8β, 14α, 21α)-26, 27-dinoronocerane-3, 8, 14, 21-tetrol (5). Compound 1 is a new serratane-type triterpene and compound 5 is isolated from this plant for the first time.
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