6-(2-氰乙基)-17α-乙酰氧基黄体酮类化合物的合成

陈兆容; 温业淳; 陈毓群

陈兆容, 温业淳, 陈毓群. 6-(2-氰乙基)-17α-乙酰氧基黄体酮类化合物的合成J. 药学学报, 1982, 17(4): 299-301.

引用本文:

陈兆容, 温业淳, 陈毓群. 6-(2-氰乙基)-17α-乙酰氧基黄体酮类化合物的合成J. 药学学报, 1982, 17(4): 299-301.

CHEN Zhao-rong, WEN Ye-chun , CHEN Yu-qun, . SYNTHESIS OF 6-(2-CYANOETHYL)-17α-ACETOXYPROGESTERONE COMPOUNDSJ. Acta Pharmaceutica Sinica, 1982, 17(4): 299-301.

Citation:

CHEN Zhao-rong, WEN Ye-chun , CHEN Yu-qun, . SYNTHESIS OF 6-(2-CYANOETHYL)-17α-ACETOXYPROGESTERONE COMPOUNDSJ. Acta Pharmaceutica Sinica, 1982, 17(4): 299-301.

6-(2-氰乙基)-17α-乙酰氧基黄体酮类化合物的合成

SYNTHESIS OF 6-(2-CYANOETHYL)-17α-ACETOXYPROGESTERONE COMPOUNDS

摘要

Abstract: Reaction of steroidal 3, 5-dienamines (Ⅱ and Ⅵ) with acrylonitrile gave 6-(2-cyanoethyl)-compounds (Ⅲa, Ⅲb and Ⅶ). Compound Ⅲb was dehydrogenated With chloranil to give-compound Ⅳ. Compounds Ⅲa, Ⅲb, Ⅳ and Ⅶ are all new compounds.

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