马成禹, 陈邦本, 王志清, 马立人. 雌甾C17位引入α-正丁基的研究——17α-正丁基雌二醇-3-环戊醚的合成J. 药学学报, 1983, 18(2): 144-146.
引用本文: 马成禹, 陈邦本, 王志清, 马立人. 雌甾C17位引入α-正丁基的研究——17α-正丁基雌二醇-3-环戊醚的合成J. 药学学报, 1983, 18(2): 144-146.
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MA Cheng-yu, CHEN Bang-ben, WANG Zhi-qing , MA Li-ren, . A STUDY OF THE INTRODUCTION OF N-BUTYL GROUP ONTO C17-POSITION OF ESTRADIOL——SYNTHESIS OF 17α-n-BUTYL-17β-ESTRADIOL-3-CYCLOPENTYL ETHERJ. Acta Pharmaceutica Sinica, 1983, 18(2): 144-146.
Citation: MA Cheng-yu, CHEN Bang-ben, WANG Zhi-qing , MA Li-ren, . A STUDY OF THE INTRODUCTION OF N-BUTYL GROUP ONTO C17-POSITION OF ESTRADIOL——SYNTHESIS OF 17α-n-BUTYL-17β-ESTRADIOL-3-CYCLOPENTYL ETHERJ. Acta Pharmaceutica Sinica, 1983, 18(2): 144-146.
shu

雌甾C17位引入α-正丁基的研究——17α-正丁基雌二醇-3-环戊醚的合成

A STUDY OF THE INTRODUCTION OF N-BUTYL GROUP ONTO C17-POSITION OF ESTRADIOL——SYNTHESIS OF 17α-n-BUTYL-17β-ESTRADIOL-3-CYCLOPENTYL ETHER

    摘要
  • Abstract: N-Butyl lithium has been proved to be a convenient reagent for introducing nbutyl group onto C17-position of estrone-3-cyclopentyl ether. Using conventional Grignard's organomagnesium reagent we obtained 3-O-cyclopentyl-3,17β-estradiol instead of the normal adduct.

     

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