WONG TZU-WU HUANG MIN-LON, . THE INTRODUCTION OF C6α-METHYL GROUP INTO DIOSGENINJ. Acta Pharmaceutica Sinica, 1962, 9(5): 265-270.
Citation: WONG TZU-WU HUANG MIN-LON, . THE INTRODUCTION OF C6α-METHYL GROUP INTO DIOSGENINJ. Acta Pharmaceutica Sinica, 1962, 9(5): 265-270.

THE INTRODUCTION OF C-METHYL GROUP INTO DIOSGENIN

  • From steroid sapogenin,diosgenin(Ⅰ),the C-methyl compound(Ⅷ,R=H or Ac) has been prepared.It was converted into the α-oxide (Ⅸ) upon treatment with thionyl chloride or phosphorus oxychloride.
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